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Chemistry · General chemistry I · Worked example

Dilute a stock solution

How would you prepare 500.0 mL of 0.300 M HCl from a 6.00 M stock solution?

M1V1=M2V2

Write what stays the same

The moles of HCl taken from the stock are the moles in the final solution, so M₁V₁ = M₂V₂, with 1 for the stock and 2 for the diluted solution.

M1V1=M2V2

Solve for the stock volume

Divide by M₁: V₁ = M₂V₂/M₁ = (0.300 M)(500.0 mL)/(6.00 M) = 25.0 mL.

V1=(0.300 M)⁢(500.0 mL)6.00 M=25.0 mL
V1=(0.300 M)⁢(500.0 mL)6.00 M=25.0 mL

Describe the procedure

Measure 25.0 mL of the 6.00 M stock with a pipet into a 500 mL volumetric flask that already holds some water, then add water to the mark and mix. With a concentrated acid, add the acid to water, not water to the acid.

Check with moles

The 25.0 mL portion holds 0.0250 L × 6.00 mol/L = 0.150 mol of HCl, and 0.150 mol in 0.5000 L is 0.300 M.

Result

Dilute 25.0 mL of the 6.00 M stock with water to a total volume of 500.0 mL.

Your turn

10.0 mL of 2.50 M NaOH is diluted to 250.0 mL. What is the new concentration?

Show the answer and explanation

0.100 M.

M₂ = M₁V₁/V₂ = (2.50 M)(10.0 mL)/(250.0 mL) = 0.100 M. The volume grew 25-fold, so the concentration fell 25-fold.

M2=(2.50 M)⁢(10.0 mL)250.0 mL=0.100 M
M2=(2.50 M)⁢(10.0 mL)250.0 mL=0.100 M

Keep exploring

Open the dilution in Solutions & concentration and change the final volume to 250.0 mL: the same 25.0 mL of stock now gives 0.600 M.

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